High-temperature superconductors with a twist

Graphical representation of the stacked, twisted cuprate superconductor, with accompanying data in the background.Credit: Lucy Yip, Yoshi Saito, Alex Cui, Frank Zhao

Science & Tech

High-temperature superconductors with a twist

Anne J. Manning

Harvard Staff Writer

January 9, 2024

3 min read

Fabrication method could facilitate materials discovery

Superconductors have intrigued physicists for decades. But these materials, which allow the perfect, lossless flow of electrons, usually only exhibit this quantum-mechanical peculiarity at temperatures so low — a few degrees above absolute zero — as to render them impractical.

A research team led by Professor of Physics and Applied Physics Philip Kim has demonstrated a new strategy for making and manipulating a widely studied class of higher-temperature superconductors, called cuprates, clearing a path to engineering new, unusual forms of superconductivity in previously unattainable materials.

Using a uniquely low-temperature device fabrication method, Kim and his team report in the journal Science a promising candidate for the world’s first high-temperature, superconducting diode — essentially, a switch that makes current flow in one direction — made out of thin cuprate crystals. Such a device could theoretically fuel fledging industries like quantum computing, which rely on fleeting mechanical phenomena that are difficult to sustain.

“High-temperature superconducting diodes are, in fact, possible, without application of magnetic fields, and opens new doors of inquiry toward exotic materials study,” Kim said.

Cuprates are copper oxides that, decades ago, upended the physics world by showing they become superconducting at much higher temperatures than theorists had thought possible, “higher” being a relative term (the current record for a cuprate superconductor is minus 225 Fahrenheit). But handling these materials without destroying their superconducting phases is extremely complex due to their intricate electronic and structural features.

The team’s experiments were led by S.Y. Frank Zhao, a former student in the Griffin Graduate School of Arts and Sciences and now a postdoctoral researcher at MIT. Using an air-free, cryogenic crystal manipulation method in ultrapure argon, Zhao engineered a clean interface between two extremely thin layers of the cuprate bismuth strontium calcium copper oxide, nicknamed BSCCO (“bisco”). BSCCO is considered a “high-temperature” superconductor because it starts superconducting at about minus 288 Fahrenheit — very cold by practical standards, but astonishingly high among superconductors, which typically must be cooled to about minus 400.

Zhao first split the BSCCO into two layers, each one-thousandth the width of a human hair. Then, at minus 130, he stacked the two layers at a 45-degree twist, like an ice cream sandwich with askew wafers, retaining superconductivity at the fragile interface.

The team discovered that the maximum supercurrent that can pass without resistance through the interface is different depending on the current’s direction. Crucially, the team also demonstrated electronic control over the interfacial quantum state by reversing this polarity. This control was what effectively allowed them to make a switchable, high-temperature superconducting diode — a demonstration of foundational physics that could one day be incorporated into a piece of computing technology, such as a quantum bit.

“This is a starting point in investigating topological phases, featuring quantum states protected from imperfections,” Zhao said.

The Harvard team worked with colleagues Marcel Franz at University of British Columbia and Jed Pixley at Rutgers University, whose teams previously performed theoretical calculations that accurately predicted the behavior of the cuprate superconductor in a wide range of twist angles. Reconciling the experimental observations also required new theory developments, performed by University of Connecticut’s Pavel A. Volkov.

The research was supported, in part, by the National Science Foundation, the Department of Defense, and the Department of Energy.

Also in this series:

Science & Tech

Blue, green, gold: Why eyes of wild cats vary in color

Study traces iris diversity to gray-eyed ancestor

October 2, 2024

5 min read

Health

Falls put older adults at increased risk of Alzheimer’s

Researchers found dementia more frequently diagnosed within one year of a fall, compared to other types of injuries

October 1, 2024

4 min read

Health

‘Weekend warriors’ can cut risk of 264 diseases

Concentrated routines just as effective as regular weekly exercise in protecting against heart, digestive conditions as well as neurological illnesses

September 26, 2024

3 min read

Science & Tech

An idea with legs

Research suggests the scuttling sea robin may serve as evolutionary model for trait development, including in humans

September 26, 2024

5 min read

Health

Using AI to repurpose existing drugs for treatment of rare diseases

Identifies possible therapies for thousands of diseases, including ones with no current treatments

September 25, 2024

7 min read